Measuring the Quenching of NO Fluorescence Produced from the Excitation of Photo-Fragmented Nitrobenzene Using a Picosecond Laser

The military is interested in using spectroscopic methods to detect nitroaromatic compounds related to explosives. Upon absorption of a UV photon, nitrobenzene can dissociate into C 6 H 5 O and NO. Wynn, et al. have shown that looking at NO fluorescence from the photodissociated nitrobenzene could be a possible detection method. However, the fluorescence can easily be quenched by molecular oxygen and other constituents in air. We have measured fluorescence lifetimes of the nascent NO resulting from photo-fragmented nitrobenzene using a pulsed picosecond tunable laser (pulse width ~15 ps) by means of a two-color process. In the two-color process, photons of a particular energy dissociated the nitrobenzene while photons of a different energy probed the A 2   +    X 2   _ (1/2,3/2) NO band system between 225-260 nm. We have performed the measurements with different background pressures of He, N 2 , and air. We present the results of these measurements which indicate considerable quenching of the NO fluorescence due to oxygen.